The interrupt will occur when the instruction after the "sti" finishes.
That's a one assembler instruction delay, i.e. a few clock cycles.
*Which* interrupt will be serviced first, however, depends on how 
many interrupt sources you have active and on the IRQ prioritization.
Ion
-- 
  It is better to keep your mouth shut and be thought a fool,
            than to open it and remove all doubt.
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